A vendor that has been through VendorInvestigate and published a favorable report has passed external verification, which is stronger than any certificate they supply.
The database is searchable by vendor, compound, date and result, and historical trends are visible.
The part that matters: analytical data are published in full, including HPLC traces, mass spectra and quantitation details.
Coverage is not comprehensive — only vendors that enough people choose to test are in the database.
Favorable reports are valuable and should increase your confidence in a vendor.